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Neighboring districts are (from the north clockwise) Mueang Ranong of Ranong Province, Phato of Chumphon Province, Chaiya, Tha Chang and Ban Ta Khun of Surat Thani Province, and Suk Samran of Ranong again. To the west is the Andaman Sea.
The southeastern part of the district is part of the Khlong Nakha Wildlife Sanctuary. The mangrove forests in the estuary of the Kapoe River are part of the Ranong Biosphere Reserve.